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Unless
specially formulated, elastomers will
typically soften when first exposed to high temperatures.
Extended heat exposure can cause irreversible changes
in tensile
strength and elongation,
as well as alterations in the chemical makeup of
a seal such that it hardens and cracks.
This hardening is the result of additional cross-linking, plasticizer evaporation,
and/or oxidation. Table
7 shows how high temperatures impact
a handful of the most-used materials.
There
are four different ASTM test
methods related to high temperature effects. All
are designed to gauge the amount of material degradation that
results from exposure to a heated environment.
The main difference between these tests is the
device used to keep pressure and heat on the specimen.
D 454 uses an air-pressure chamber to mimic the
degrading effects of heat and air. D 572 utilizes
a similar oxygen-pressure chamber to simulate deterioration
by heat and oxygen. D 573 details testing in an
air oven, and D 865 describes heat and air testing
within a test tube enclosure.
THERMAL
PROPERTIES MAIN PAGE
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“Because
O-rings often face extreme heat or extreme cold, there are important thermal properties
you must consider.”

Table 7
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