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Plasticizer extraction can
affect all seals, especially those used in fuel
systems. Plasticizer is initially added to an
O-ring compound in
order to augment its flexibility and resilience.
If plasticizer is extracted (chemically removed)
by system fluids,
the seal’s flexibility and resilience both
suffer. The O-ring hardens,
small cracks start to appear in the stressed area
of the cross-section,
and the seal’s overall volume decreases.
This
loss of volume (shrinkage),
coupled with the aforementioned hardening, is typically
accompanied by a loss in retained sealing force,
i.e. the seal will leak. The best available solution
is to use a seal material that is still compatible with
all elements of the system but that contains little
or no extractable plasticizer. Figure
136 is an example of O-ring failure
due to plasticizer extraction.
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“If
plasticizer is extracted (chemically removed) by system fluids,
the seal’s flexibility and resilience both suffer.”

Figure
136
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